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Raw gas feeds contain higher levels of butadiene and heavier components which can be as reactive as acetylene in hydrogenation reactions. Raw gas reactors are known for higher temperature rises across the converter and thus have poor reactor stability and selectivity if an inappropriate catalyst is used. The FE E-RG formulation was custom tailored to provide high selectivity in the “high delta T” environment.
The commercial operators of E-Series catalyst benefit from high selectivity and lower converter heat rise such that less reactor fouling occurs from butadiene. This enables the converter run lengths to be substantially increased compared to those using other types of acetylene hydrogenation catalysts. Chevron Phillips Chemical’s success with the E-Series catalyst goes far beyond its own acetylene converters. Chevron Phillips Chemical has the ability to custom formulate catalysts based on customer needs and process design, to offer catalysts with higher selectivity, improved stable operations without runaways, longer cycle run lengths and longer overall catalyst life. The fact that Chevron Phillips Chemical is both an ethylene producer and catalyst supplier is a great benefit to our customers since we have personal insight into reactor operations. Ethylene crackers can be broadly divided into two basic configurations, those with front-end acetylene converters and those with back-end converters.
Front-end acetylene conversion involves the hydrogenation of acetylene prior to the removal of methane and lighter components from the cracked gas stream (at the front of an ethylene plant) while in back-end plants, the acetylene conversions occurs in a stream at the back end of the plant where basically only ethane, ethylene, acetylene and possibly some carbon monoxide enters the acetylene converter. The differences in feed compositions require different catalyst formulations in order to provide optimum and stable performance. As a worldwide manufacturer and marketer of specialty chemicals, Chevron Phillips Chemical maintains an experienced staff ready to assist with various order processing and shipping alternatives. Our group of knowledgeable chemists and engineers is also ready to assist customers with technical service issues. With significant experience as a major ethylene producer, Chevron Phillips Chemical is uniquely qualified to understand the customer’s catalyst and processing needs. Laboratory experimentation, pilot plant operations, and advanced modeling techniques are also available to address customer inquiries. Our support extends to our experienced professionals assisting with operator training, plant startups, and acetylene converter kinetic and thermodynamic modeling general troubleshooting.
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The high selectivity and stability of E-Series catalyst allow the operator to meet extremely low acetylene levels in the reactor effluent while reducing acetylene converter down-time and off-spec production without sacrificing production stability. Excellent Selectivity – E-Series catalyst quantitatively removes acetylene while limiting the amount of over-hydrogenation of ethylene to ethane. This enhanced selectivity results in an increased amount of ethylene production as well as in the reduction of reprocessing cost of the recycle ethane. Stable ARU Operations – E-Series catalysts are much more stable when operating at the higher conversions necessary to lower the acetylene to tighter ethylene specifications. Operation of other catalysts at this conversion level can result in temperature excursions that can lead to dangerous temperature “runaway” conditions. Sites to download h games.
Resistance to CO Changes – Reactors operated with E-Series catalyst are highly resistant to temperature excursions due to fluctuations in carbon monoxide content in the feed. Changes in carbon monoxide levels with traditional catalysts can often lead to off-spec production and temperature runaway conditions.
For example, following the decoking of a furnace, an operator can easily adjust the temperature of the acetylene reactor containing E-Series catalyst to accommodate changes in the carbon monoxide content of the feed. This allows the reactor to be operated with little or no off-spec production.
Ease of Reactor Startup – Using E-Series catalyst enables a quicker startup while minimizing off-spec production compared to traditional catalysts. Ease of Use – E-Series catalysts can easily be regenerated by either ex- or in-situ methods. The high crush strength of the catalyst enables them to maintain their integrity through multiple handlings.
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